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dc.contributor.authorNecefoğlu , Hacali
dc.contributor.authorHökelek , Tuncer
dc.contributor.authorÖztür , Vildan
dc.contributor.authorÖzbek , Füreya Elif
dc.contributor.authorAdıgüzel , Vedat
dc.date.accessioned2019-12-13T06:36:01Z
dc.date.available2019-12-13T06:36:01Z
dc.date.issued2011
dc.identifier.issn1600-5368
dc.identifier.urihttps://doi.org/10.1107/S1600536811044771
dc.identifier.urihttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247555/
dc.identifier.urihttp://hdl.handle.net/11655/18625
dc.description.abstractIn the mononuclear NiII title complex, [Ni(C7H4FO2)2(C6H6N2O)2(H2O)2], the NiII atom, located on an inversion center, is coordinated by two nicotinamide and two 4-fluoro­benzoate ligands and two water mol­ecules in a distorted N2O4 octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 8.95 (8)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 75.01 (7)°. The water mol­ecule links the adjacent carboxyl­ate O atom via an intra­molecular O—H⋯O hydrogen bond. In the crystal, O—H⋯O, N—H⋯O, C—H⋯O and C—H⋯F hydrogen bonds link the mol­ecules into a three-dimensional network. π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.7287 (11) Å] is also observed.
dc.relation.isversionof10.1107/S1600536811044771
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleTrans-Diaqua­Bis­(4-Fluoro­Benzoato-Κo)Bis­(Nicotinamide-Κn 1)Nickel(Ii)
dc.typeinfo:eu-repo/semantics/article
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.typeinfo:eu-repo/semantics/publishedVersion
dc.relation.journalActa Crystallographica Section E: Structure Reports Online
dc.contributor.departmentFizik Mühendisliği
dc.identifier.volume67
dc.identifier.issuePt 11
dc.identifier.startpagem1638
dc.identifier.endpagem1639
dc.description.indexPubMed
dc.description.indexWoS
dc.description.indexScopus


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