Kapiler Elektrokromatografi İçin Yeni Monolitik Sabit Fazların Sentezi ve Karakterizasyonu
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In the scope of this thesis, the synthesis of polymethacrylate based capillary monoliths was performed via block copolymerization by using a new hydrophilic monomer with reactive chloropropyl moiety, 3-chloro-2-hydroxypropyl methacrylate (HPMA-Cl). These columns were successfully tried in the electrochromatographic separation of alkylbenzenes, phenols, polyaromatic hydrocarbons, nucleosides, nucleotides and the highest theoretical plate counts was achieved as 205.000 plates m in these separations. The results indicated that a new reactive monolith in the form of polyacrylate was obtained and the synthesis of new electrochromatographic stationary phases could be achieved by using this reactive monolith. Hence, a new alternative to the commonly utilized reactive structures like poly(chloromethylstyrene-co-divinylbenzene) and poly(glycidyl methacrylate-co-ethylene dimethacrylate) was developed.